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WARNING: When used to extinguish fires {fire}, phosgene, which is very toxic,
tend to be formed on 1
Hazardous Reactions
Aluminum chloride and Triethylaluminum. A mixture of carbon tetrachloride blasted
when heated to a temperature of 2 rooms {place}
Benzoyl Peroxide and Ethylene. Mixture of ethylene and carbon tetrachloride may
Blast at elevated temperatures on the initiation with benzoyl peroxide 3
Boranes. Explosions could result from the use of carbon tetrachloride as the elution
solvent in the chromatographic separation boranes.4
Chlorine Trifluoride. Solutions of chlorine trifluoride in carbon tetrachloride can be
Blasted 5
Decaborane. Sensitive to the effects of a mixture formed with carbon tetrachloride, 1 June 1911 -
Diamino-3 ,6,9-triazimdecane ("Tetraethylenepentamine"). Amine in carbon
tetrachloride reacted vigorously 1 hour after mixing 7.8
N, N-Dimethylformamide. Iron can catalyze very exothermic, and sometimes strong
reaction between carbon tetrachloride and dimethylformamide.9
Fluoride. Contact fluorine gas with carbon tetrachloride results in a strong or
explosive reaction 5
Metals. Heating the powder Ala with carbon tetrachloride to 152 ° C can cause
sulphuric acid Blast cleaning 10 blocks barium by carbon tetrachloride over a
strong reaction mixtures 11 K or K-Na and carbon tetrachloride - is extremely shocksensitive.
12 Zinc paste and carbon tetrachloride will burn readily after fire 13
Potassium tert-Butoxide. Supplement cuts} {drops of carbon tetrachloride to 1.5 g
potassium tert-butoxide ended inflammation after 1 minutes 14
Hazardous laboratory chemicals disposal of lead 130
Physiological Properties and Health Hazards
Vapor irritates the eyes and can cause headache, mental confusion confusion {}, nausea, vomiting,
and finally coma. The liquid irritates the eyes, and if ingested, causing nausea, vomiting,
and injury {} damage the liver, kidneys, heart and nervous system. Small doses can result in
death. Prolonged exposure can cause a couple of vomiting, bronchitis, and jaundice.
Animal carcinogen, reasonably expected to be a human carcinogen 15 Avoid breathing
pairs.
Avoid contact with skin and eyes.16 TLV-TWA 5 ppm (31 mg/m3); TLV-STEL 10
ppm (63 mg/m3) .17
Instruction Break
Instruct others to keep a safe distance. Wear breathing apparatus, eye protection,
lab coat, and PVA, or Viton ® gloves.18 Coverage sheds with 1:1:1 mixture by weight
of sodium carbonate or calcium carbonate, clay cat litter (bentonite), and sand. Scoop in
fit the container and label for disposal burning.19-21
Waste Disposal
Wear of PVA or Viton ® gloves, 18 lab coats, and eye protection. Avoid breathing
pairs. Recycle distillation (in the hood smoke), or place waste {} in halogenated waste solventdisposal
container for disposal by burning. Dissolve Dissolve {} of a chlorine-free
flammable solvent and aerosol sprays {} in the furnace with afterburner and scrubber 20.21
LINKS {Recommendations}
1. Merck 1826.
2. Reineckel, H., Angew. Chem. (Int. Editor), March 65, 1964.
3. Fasteners, R.O. and others., Chem. News of the Engineer, 25, 1866, 1947.
4. B 1529.
5. Mellor, edition 2, Suppl. 1, 156, 1956.
6. Hawthorne, M.F., Inorg. Synth., 10, 93, 1967.
7. B 123.
8. Collins, R.F., Chem. Ind., 704, 1957.
9. B 122.
10. Anonymous, Angew. Chem., 62, 584, 1950.
11. B 78.
12. Staudinger, H., Z. Electrochem., 31, 549, 1925.
13. Berger, E., Branch. Break., 170, 29, 1920.
14. Manwaring, R. and others., Chem. Ind., 172, 1973.
15. NIEHS III-82 ..
16. Suite 281.
17. ACGIH 21.
18. LSS.
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